长沙理工大学学报(自然科学版)
热致形状记忆聚氨酯改性沥青自愈合性能研究
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(长沙理工大学 交通学院 ,湖南 长沙 410114)

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通讯作者:

冯新军(1971—)(ORCID:0000-0001-8750-8437),男,教授,主要从事道路工程材料方面的研究。E-mail:fxjasphalt@aliyun.com

中图分类号:

U414

基金项目:

国家自然科学基金项目(52178415);湖南省自然科学基金项目(2021JJ30709);河南省交通运输学会科研项目(YJXHZD202401)


Study on self -healing properties of thermally induced shape memory polyurethane modified asphalt
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(School of Transportation , Changsha University of Science & Technology , Changsha 410114, China)

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    摘要:

    【目的】提高沥青材料自愈合性能,实现实际服役中开裂沥青路面的及时有效自愈合。【方法】采用预聚体法制备的热致形状记忆聚氨酯 (shape memory polyurethane,SMPU)预聚物对基质沥青进行改性,制得热致形状记忆聚氨酯改性沥青 (shape memory polyurethane modified asphalt,SMPU -MA);采用动态剪切流变仪以时间扫描模式对 SMPU -MA进行疲劳 -愈合 -疲劳循环加载测试;以间歇前后动态剪切模量的衰减速率 H4(H4越小,自愈合性能越好 )为指标,分析不同条件下 SMPU -MA的自愈合性能变化趋势,并建立其形状恢复率与自愈合性能指标的联系。【结果】在相同损伤度下,间歇时间越长,SMPU -MA自愈合性能越好;当损伤度为60%,间歇时间为 600、3 600 s时,SMPU -MA的H4较基质沥青的分别减小 30.92%、72.11%。在相同间歇时间下,损伤度越大,SMPU对沥青自愈合性能的提升效果越显著;当间歇时间为 3 600 s,损伤度为 20%、40%、60%时,SMPU -MA的H4较基质沥青的分别减小 54.38%、56.47%、72.11%。此外,SMPU -MA的形状恢复率与 H4成线性负相关,决定系数高达 0.953 9。【结论】采用 SMPU对基质沥青进行改性以改善沥青形状记忆特性,对提升沥青材料的自愈合性能起到了至关重要的作用。

    Abstract:

    [Purposes ] This paper aims to enhance the self -healing performance of asphalt materials and achieve timely and effective healing of cracks in asphalt pavements during service.[Methods] The thermally induced shape memory polyurethane (SMPU) prepolymer was prepared by the prepolymer method to modify the matrix asphalt,and the SMPU -modified asphalt (SMPU -MA) was prepared.The dynamic shear rheometer (DSR) was used to test SMPU -MA under fatigue,healing,and fatigue cyclic loading in time -scanning mode.The decay rate of dynamic shear modulus H4 (a smaller H4 value indicates better self -healing performance ) before and after the intermittent interval was used as an index to analyze the changing trend of SMPU -MA’s self -healing performance under different conditions.The relationship between shape recovery rate and self-healing performance of SMPU -MA was established.[Findings] The self -healing performance of SMPU -MA improves with increasing rintermittent interval at the same damage level.At a damage level of 60%,the self -healing index H? of SMPU -MA decreases by 30.92% and 72.11% compared with that of the matrix asphalt after intermittent intervals of 600 s and 3 600 s,respectively.Under the same intermittent interval,a higher damage level leads to a more pronounced improvement in the self -healing performance of SMPU -MA.When the intermittent interval is 3 600 s,and the damage levels are 20%,40%,and 60%,the self -healing index H? of SMPU -MA decreases by 54.38%,56.47%,and 72.11%,respectively,compared with the matrix asphalt.The shape recovery rate of SMPU -MA is linearly and negatively correlated with H4,and the coefficient of determination is as high as 0.953 9.[Conclusions ] Modifying the matrix asphalt with SMPU to enhance its shape memory characteristics plays a crucial role in improving the self -healing performance of asphalt materials.

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冯新军,朱俊杰,任泓宇,等.热致形状记忆聚氨酯改性沥青自愈合性能研究[J].长沙理工大学学报(自然科学版),2025,22(5):44-53.
FENG Xinjun, ZHU Junjie, REN Hongyu, et al. Study on self -healing properties of thermally induced shape memory polyurethane modified asphalt[J]. Journal of Changsha University of Science & Technology (Natural Science),2025,22(5):44-53.

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  • 收稿日期:2025-01-13
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  • 在线发布日期: 2025-11-27
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