长沙理工大学学报(自然科学版)
PEMFC环境下氮化物涂层的耐蚀和导电性能研究
作者:
作者单位:

1.常州大学 材料科学与工程学院,江苏 常州 213164;2.江苏省技术转移(常州大学)研究院,江苏 常州 213164

作者简介:

潘太军(1977-) (ORCID:0000-0002-0604-160X),男,教授,主要从事燃料电池和腐蚀防护方面的研究。E-mail:tjpan@cczu.edu.cn

通讯作者:

潘太军(1977-) (ORCID:0000-0002-0604-160X),男,教授,主要从事燃料电池和腐蚀防护方面的研究。E-mail:tjpan@cczu.edu.cn

中图分类号:

O646

基金项目:

常州市科技计划项目(CZ20190017);江西省材料表面工程重点实验室开放基金资助项目


Study on anti-corrosion and conductivity performance of the nitride coating in PEMFC environment
Author:
Affiliation:

1.School of Materials Science and Engineering, Changzhou University, Changzhou 213164,China;2.Jiangsu Provincial Institute of Technology Transfer (Changzhou University),Changzhou 213164, China

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    摘要:

    【目的】揭示氮化物涂层在质子交换膜燃料电池(proton exchange membrane fuel cell,PEMFC)环境中潜在的应用价值,阐明其耐蚀和导电机制。【方法】采用等离子体气相沉积技术在SS304不锈钢表面制备氮化物涂层,利用扫描电子显微镜(scanning electron microscope,SEM)、能量色散X射线谱(X-ray energy dispersive spectrum,EDS)和X射线衍射(X-ray diffraction,XRD)等微观手段对氮化物涂层的形貌和组织结构进行表征,通过电化学测试和界面接触电阻测量等手段评价涂层的耐蚀性和导电性。【结果】氮化物涂层均匀致密,与基体结合紧密,具有一定的疏水性,有效提高了不锈钢基体在酸性溶液中的耐蚀性,使得不锈钢基体的自腐蚀电位升高了187 mV。在酸性溶液的浸泡下,氮化物涂层的开路电位始终比基体的高,且腐蚀前后氮化物涂层都保持着良好的导电性,其界面接触电阻都比基体的低。【结论】施加氮化物涂层的SS304不锈钢的导电性和耐蚀性明显比基体的好,这与氮化物涂层本身具有良好的化学稳定性有关。

    Abstract:

    [Purposes] The potential application of the nitride materials in proton exchange membrane fuel cell environment has been revealed, which also clarifies their corrosion resistance and conductivity mechanism.[Methods] In this study, the nitride coatings were prepared on the surface of SS304 stainless steel by plasma vapor deposition technology. The morphologies and structures of the coatings were characterized by scanning electron microscopy (SEM), X-ray energy dispersive spectrum (EDS) and X-ray diffraction (XRD). The corrosion resistance and conductivity of the coatings were evaluated by electrochemical test and interface contact resistance measurement.[Findings] The coating was uniform and compact, which had certain hydrophobicity and strongly adhered to the substrate. It had effectively improved corrosion resistance of stainless steel in acidic solution, which had increased self-corrosion potential of the substrate with 187 mV. The open circuit potential of the coating was always higher than that of the substrate during the whole immersion in acid solution. The nitride coatings maintained good electrical conductivity before and after corrosion, and its interface contact resistance was also lower than that of the stainless steel substrate.[Conclusions] The conductivity and corrosion resistance of nitride-coated SS304 stainless steel is significantly better than that of substrate, which is related to the good intrinsic chemical stability of the nitrides.

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王兵,江健,潘太军. PEMFC环境下氮化物涂层的耐蚀和导电性能研究[J].长沙理工大学学报(自然科学版),2022,19(3):31-39.
WANG Bing, JIANG Jian, PAN Taijun. Study on anti-corrosion and conductivity performance of the nitride coating in PEMFC environment[J]. Journal of Changsha University of Science & Technology (Natural Science),2022,19(3):31-39.

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  • 在线发布日期: 2022-10-24
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