Aiming at the problems such as low strength， single function， high cost， compli-cated process and large shrinkage， the traditional cement-based materials are based on ava-riety of active powder， optimal mix proportion of high strength cementitious materials was determined with the index of strength by single-factor， orthogonal experiments and range a-nalysis method， which was：cement：FA：silicon fume：sand：PP：water reduce agent：UEA：silicasol：SBR：water=100：12：6：46.75：0.08：1.36：3：0.7：1.3：285，and itis28d compressive/flexural strength achieved 12.4MPa/110.06MPa.On the basis of optimal mix proportion， through the drying shrinkage properties test， DSC， SEM， XRD and other methods， further analysis of the properties of high strength cement based materi-als， which show that the drying shrinkage of specimen added 3%UEA was decreased 0.077%compared with specimen added 0%UEA to 0.176%.And the secondary hydration level of high strength cementitious materials is poor， but the high strength and toughness performance were obtained from favorable accumulation and densified homogeneous struc-ture in the microscopic dimension.